Two Magnetic Switching Complexes Based on the FeII Ion
收藏Figshare2016-08-09 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Two_Magnetic_Switching_Complexes_Based_on_the_Fe_sup_II_sup_Ion/3506501
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Two neutral mononuclear iron(II) complexes with different spin-crossover (SCO) properties, Fe(L1)2(SCN)2 (1) and Fe(L2)2(SCN)2 (2) (L1 = 2-(thiophen-3-yl)-1H-imidazo[4,5-f][1,10]phenanthroline and L2 = 2-(thiophen-2-yl)-1H-imidazo[4,5-f][1,10]phenanthroline), were solvothermally synthesized. With the different substituted position in 1,10-phenanthroline derivatives, 1 exhibits gradual SCO around room temperature with T1/2 = 280 K, while 2 displays abrupt SCO with 10 K hysteresis at T1/2↓ = 210 K and T1/2↑ = 220 K.
创建时间：
2016-08-09
