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Catalyst-Free Aromatic Nucleophilic Substitution of <i>meso</i>-Bromoporphyrins with Azide Anion: Efficient Synthesis and Structural Analyses of <i>meso</i>-Azidoporphyrins

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meso-Mono- or diazidoporphyrins were readily obtained in high yields by the catalyst-free aromatic nucleophilic reaction of the corresponding bromoporphyrins with azide anions under mild conditions. The molecular structures of the obtained azides were unambiguously determined by X-ray crystallographic analysis.

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2012-01-06
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