Ligand Rearrangement Leads to Tetrahydrothiophene-Functionalized N,S-Heterocyclic Carbene Palladium(II) Complexes
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下载链接：
https://figshare.com/articles/dataset/Ligand_Rearrangement_Leads_to_Tetrahydrothiophene-Functionalized_N_S-Heterocyclic_Carbene_Palladium_II_Complexes/14522578
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资源简介：
Tetrahydrothiophene-functionalized
N,S-heterocyclic carbene palladium(II)
complexes are synthesized through an unexpected rearrangement that
proceeds with palladium(II) trifluoroacetate but not with palladium(II)
acetate, palladium(II) bromide, or palladium(II) chloride. A series
of these complexes were isolated and characterized by X-ray crystallography.
The mechanism of formation of these [3.2.1]palladabicycles was explored,
and the catalytic capabilities of these complexes were demonstrated
in representative C–C coupling reactions.
创建时间：
2021-04-30
