Iron-Catalyzed Regioselective Remote C(sp2)‑H Carboxylation of Naphthyl and Quinoline Amides
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https://figshare.com/articles/dataset/Iron-Catalyzed_Regioselective_Remote_C_sp_sup_2_sup_H_Carboxylation_of_Naphthyl_and_Quinoline_Amides/9232448
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Iron(III)-catalyzed regioselective direct remote C–H carboxylation of naphthyl and quinoline amides was developed using CBr4 and alcohol. The reaction involves a radical pathway using a coordination activation strategy and single electron transfer process. The use of sustainable iron catalysis, selectivity, and the substrate scope are the important practical features.
创建时间:
2019-07-26



