Generation and Trapping of a Terminal Chlorophosphinidene Complex

NIAID Data Ecosystem2026-03-06 收录

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Generation and Trapping of a Terminal Chlorophosphinidene Complex

创建时间：

2016-02-26

Remarkable Product Diversity in the “Self-Organized” Reaction of Deprotonated Acetonitrile with Chlorophosphines

配体合成

有机金属反应机理

This study examined the reaction of in situ deprotonated acetonitrile with different chlorophosphines ClPR2 (5a−d) to find new nitrile functionalized bis(diphenylphosphino)methane (dppm) ligands. Depe

NIAID Data Ecosystem80

Trisubstituted Boroles by 1,1-Carboboration

硼化学

有机金属反应机理

A 1,3,4-trisubstituted borole is readily obtained by a 1,1-carboboration sequence starting from a bis(ethynyl)borane and B(C6F5)3. Subsequent photolysis converts it to the 1,2,5-trisubstituted boro

NIAID Data Ecosystem50

Formation of BCBH/BCBCl Four-Membered Rings by Complexation of Boron- and Nitrogen-Substituted Acetylene with Hydro-/Chloroboranes

硼化学

有机金属反应机理

Reactions of boron- and nitrogen-substituted acetylene toward hydro-/chloroboranes are described. The X-ray crystallography revealed the formation of BCBH/BCBCl four-membered rings in the solid state.

NIAID Data Ecosystem30

Cyclometalated Tantalum Diphenolate Pincer Complexes: Intramolecular C−H/M−CH 3 σ-Bond Metathesis May Be Faster than O−H/M−CH 3 Protonolysis

有机金属反应机理

环金属化反应

A diphenol linked at the ortho positions to a benzene ring was metalated with TaCl2(CH3)3. Deuterium labeling of the phenol hydrogens and of the linking 1,3-benzenediyl ring reveals an unexpected mech

NIAID Data Ecosystem70

Cycloaddition Reactions of Terminal Alkynes and Phosphaalkynes with an Isolable 5-Coordinate β-Diiminate Platinum(IV) Dihydrosilyl Complex

铂(IV)配合物环加成

有机金属反应机理

Combining (Cl-nacnac)Pt(H)(1-pentene) (Cl-nacnac = N-p-Cl-phenyl-β-diiminate) and HSiR3 (SiR3 = SiPh3, SiEt3, SiHPh2) leads to rapid displacement of 1-pentene; oxidative addition of the Si−H bond prod

NIAID Data Ecosystem40

Generation and Trapping of a Terminal Chlorophosphinidene Complex

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