C−C Bond-Forming Reductive Elimination from a Zirconium(IV) Redox-Active Ligand Complex
收藏NIAID Data Ecosystem2026-03-06 收录
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Carbon−carbon bond-forming reductive elimination of biphenyl is observed upon two-electron oxidation of the [ZrIVPh2(ap)2]2- dianion. Crossover experiments confirm that the C−C bond-forming step occurs at a single zirconium metal center. The reactivity is enabled by the participation of a redox-active amidophenolate ligand set.
创建时间：
2016-03-01
