Triple-Stranded Cluster Helicates for the Selective Catalytic Oxidation of C–H Bonds
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Triple-stranded cluster helicates with heptametallic dicubane cores are synthesized by entrapping metals in the cavities of linear triple helicates based on a C2-symmetrical hexadentate Schiff-base ligand of ortho-substitued biphenol. The helicates are stable in both the solution and solid states, and the copper species could selectively catalyze the oxidation of C–H bonds of alkanes to ketones.
创建时间：
2016-10-11
