Tandem C(sp<sup>2</sup>)–OMe Activation/C(sp<sup>2</sup>)–C(sp<sup>2</sup>) Coupling in Early Transition-Metal Complexes: Aromatic C–O Activation beyond Late Transition Metals
收藏NIAID Data Ecosystem2026-03-09 收录
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We report on combined structural, kinetic, and computational studies unraveling the mechanism of a unique, highly selective intramolecular C(sp2)–OMe cleavage/C(sp2)–C(sp2) coupling tandem reaction in group 3 metal (Y and Sc) complexes of amidine-amidopyridinate ligands. The latter process represents a rare stoichiometric model of the nonredox cleavage of inert C(sp2)–O bonds relevant to cross-coupling reactions of aromatic ethers catalyzed by late transition metals.
创建时间：
2016-03-31
