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Direct Reaction of Aroyl Cyanides with Azazirconacyclopentadienes: Synthesis and Structural Characterization of Stabilized Azazirconacyclopentenes

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Direct_Reaction_of_Aroyl_Cyanides_with_Azazirconacyclopentadienes_Synthesis_and_Structural_Characterization_of_Stabilized_Azazirconacyclopentenes/3243610
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The direct reaction of aroyl cyanide with azazirconacyclopentadiene takes place at room temperature in THF. The X-ray crystal structure analysis of the product 2e shows a novel azazirconacycle with a bidentate O−C−N unit. Hydrolysis of the newly formed zirconacycle affords the N-substituted benzamide derivative in good yield.
创建时间:
2016-05-05
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