Direct Reaction of Aroyl Cyanides with Azazirconacyclopentadienes: Synthesis and Structural Characterization of Stabilized Azazirconacyclopentenes
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The direct reaction of aroyl cyanide with azazirconacyclopentadiene takes place at room temperature in THF. The X-ray crystal structure analysis of the product 2e shows a novel azazirconacycle with a bidentate O−C−N unit. Hydrolysis of the newly formed zirconacycle affords the N-substituted benzamide derivative in good yield.
创建时间：
2016-05-05
