Synthesis of (−)-Neothiobinupharidine
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https://figshare.com/articles/dataset/Synthesis_of_Neothiobinupharidine/2448754
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资源简介：
An eight step, asymmetric synthesis of a dimeric thiaspirane
nuphar
alkaloid from 3-methyl-2-cyclo-pentenone is reported. The brevity
of the route relies on a useful procedure for tandem reductive allylation
of cyclopentenones, as well as the minimization of redox manipulations
and other functional group interconversions. The distribution of products
that arise from spontaneous dimerization points to a more complex
biosynthesis.
创建时间：
2013-01-30
