Pd–PEPPSI-Type Expanded Ring N‑Heterocyclic Carbene Complexes: Synthesis, Characterization, and Catalytic Activity in Suzuki–Miyaura Cross Coupling
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https://figshare.com/articles/dataset/Pd_PEPPSI_Type_Expanded_Ring_N_Heterocyclic_Carbene_Complexes_Synthesis_Characterization_and_Catalytic_Activity_in_Suzuki_Miyaura_Cross_Coupling/2284972
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资源简介：
The
synthesis and characterization of the new six- and seven-membered
Pd–PEPPSI-type N-heterocyclic carbene (NHC) complexes 3 and 4 is described. Complexes of the general
formula [Pd(NHC)(3ClPy)Cl2] (NHC = 6- or 7-Mes, 3ClPy =
3-chloropyridine) are accessed via the oxidation of the well-defined
parent palladium(0) complexes 1 and 2. Complexes 3 and 4 have been employed in Suzuki–Miyaura
cross-coupling and catalytic dehalogenation of a range of aryl halide
substrates.
创建时间：
2016-02-17
