Tin Trihydride as a Ligand in Osmium Complexes
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https://figshare.com/articles/dataset/Tin_Trihydride_as_a_Ligand_in_Osmium_Complexes/3063067
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资源简介：
Tin trihydride Os(SnH3)(Tp)L(PPh3) [L = P(OMe)3,
P(OEt)3] complexes were prepared by allowing chloro OsCl(Tp)L(PPh3) complexes to react first with SnCl2 and then with
NaBH4 in ethanol. The complexes were characterized spectroscopically and by the X-ray crystal structure determination of
the Os(SnH3)(Tp){P(OMe)3}(PPh3) derivative. Reaction of tin
trihydride complexes with CO2 led to formate Os[SnH{OC(H)O}2](Tp)L(PPh3) derivatives.
创建时间：
2016-02-29
