Interaction of Azobenzene and Benzalaniline with Strong Amido Bases
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The interaction of azobenzene with lithium dicyclohexylamide (Cy2NLi) in THF or Et2O afforded the ion–radical salt of azobenzene (1) structurally characterized for the first time and dicyclohexylaminyl radical, which begins a novel chain of transformations leading eventually to the imino–enamido lithium complex (3). Benzalaniline, being a relative of azobenzene, reacted with Cy2NLi without electron transfer by a proton-abstraction mechanism to form the dilithium salt of N1,N2,1,2-tetraphenylethene-1,2-diamine quantitatively.
创建时间：
2016-02-12
