Amination of Nitro-Substituted Heteroarenes by Nucleophilic Substitution of Hydrogen
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https://figshare.com/articles/dataset/Amination_of_Nitro-Substituted_Heteroarenes_by_Nucleophilic_Substitution_of_Hydrogen/21304696
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资源简介：
An open-air method for the transition metal-free direct
amination
of nitro(hetero)arenes by anilines is disclosed. In this methodology,
an aromatic C–H bond is substituted via oxidative nucleophilic
aromatic substitution of hydrogen (ONSH). Density functional theory
calculations and mechanistic studies support a dianion pathway with
oxidation by molecular oxygen as the rate-limiting step.
创建时间：
2022-10-10
