A Catalyst-Free Benzylic C–H Bond Olefination of Azaarenes for Direct Mannich-like Reactions
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https://figshare.com/articles/dataset/A_Catalyst_Free_Benzylic_C_H_Bond_Olefination_of_Azaarenes_for_Direct_Mannich_like_Reactions/2621940
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A highly efficient synthesis of trans-alkenylazaarene under catalyst-free conditions was developed via the addition of methylazaarenes to N-sulfonyl aldimines and a subsequent C–N elimination in situ. A one-pot procedure for this addition–elimination was also developed. The reaction could tolerate a broad substrate scope and give the corresponding alkenylazaarenes in high yields.
创建时间：
2016-02-23
