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Remarkable Stereoselectivity in Intramolecular Borono-Mannich Reactions: Synthesis of Conduramines

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Figshare2016-02-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Remarkable_Stereoselectivity_in_Intramolecular_Borono_Mannich_Reactions_Synthesis_of_Conduramines/2557750
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An unprecedented intramolecular Petasis condensation provides a novel approach to biologically important conduramines. The compounds are produced with an exclusive anti stereoselectivity for the newly created β-amino alcohol motif. The stereochemical outcome of the reaction is opposite to the one usually observed in the intermolecular reaction.
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2016-02-22
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