A General Diastereoselective Catalytic Vinylogous Aldol Reaction Among Tetramic Acid-Derived Pyrroles
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https://figshare.com/articles/dataset/A_General_Diastereoselective_Catalytic_Vinylogous_Aldol_Reaction_Among_Tetramic_Acid_Derived_Pyrroles/2038920
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资源简介：
A catalytic diastereoselective aldol
reaction has been developed for N1-arylated/C2-O-silylated/C3-methylated and brominated/C4-O-methylated pyrroles in its reactions with various aldehydes. Syn
adducts emerge with regard to the vicinal nitrogen and oxygen heteroatom
substituents. The N1-aryl residue undergoes oxidative
cleavage, and the C3-bromine atom undergoes palladium-mediated coupling
reactions, both without disturbing the newly created stereocenters.
创建时间：
2015-12-17
