Cyclo[4]carbazole, an Iodide Anion Macrocyclic Receptor
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https://figshare.com/articles/dataset/Cyclo_4_carbazole_an_Iodide_Anion_Macrocyclic_Receptor/3843912
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资源简介:
A novel preorganized
and rigid iodide anion macrocyclic receptor,
cyclo[4]carbazole (Cy[4]C), is reported here. The structure
of Cy[4]C was confirmed by single-crystal X-ray analysis.
The binding affinity of Cy[4]C for iodide anion was investigated
by UV–vis and 1H NMR spectroscopic techniques. The
crystal structure of the complex between Cy[4]C and chloroform
also provided evidence for the recognition ability of Cy[4]C toward iodide anion. Furthermore, the 1:1 complexation stoichiometry
between Cy[4]C and iodide anion was confirmed by high-resolution
mass spectrometry and molecular modeling.
创建时间:
2016-10-03



