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Two Mercury Antimony Chalcogenides Cs2HgSb4S8 and Cs2Hg2Sb2Se6 with Cesium Cations as Counterions

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Figshare2018-11-09 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Two_Mercury_Antimony_Chalcogenides_Cs_sub_2_sub_HgSb_sub_4_sub_S_sub_8_sub_and_Cs_sub_2_sub_Hg_sub_2_sub_Sb_sub_2_sub_Se_sub_6_sub_with_Cesium_Cations_as_Counterions/7321874
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Two novel layer structure compounds, Cs2HgSb4S8 and Cs2Hg2Sb2Se6, were synthesized in organic solvent under solvothermal conditions. The Cs2HgSb4S8 is formed of [HgSb4S8]2– ribbons and S atoms by corner sharing. The Cs2Hg2Sb2Se6 is made up of [SbHg2Se6]5– ribbon and disorder trigonal-pyramidal SbSe3 by sharing μ3-Se. These compounds are characterized by single-crystal X-ray diffraction, powder X-ray diffraction, solid-state optical absorption spectra, and so on.
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2018-11-09
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