Short-Range Electronic Interactions between Vanadium and Molybdenum in Bimetallic SAPO‑5 Catalysts Revealed by Hyperfine Spectroscopy

<strong>Data type</strong>: Experimental spectroscopic measurements, Computer Simulation and Analysis Files are with filename extensions: <strong>DSC</strong>, <strong>DTA</strong>, and <strong>m</strong>. Information on <strong>origin of the data</strong>: EPR spectroscopic measurements with filename extensions <strong>DSC</strong> and <strong>DTA</strong> EPR spectroscopic simulation and analyses with filename extension<strong> m</strong> Are the data <strong>generated</strong> (e.g. by a machine) or <strong>collected</strong> (e.g. by means of a survey)? X-band CW-EPR spectroscopic measurements were generated by EMX spectrometer equipped with SHQ cavity produced by Bruker. Q-band Pulsed-EPR spectroscopic measurements were generated by ELEXYS 580 EPR spectrophotometer equipped with ER5106QT cavity and ER035 M NMR gaussmeter produced by Bruker. <strong>If the dataset includes multiple files that relate to each other:</strong> Files in <strong>PARACAT_WP4_20230612_01_CW </strong>folder includes CW-EPR spectroscopic measurements and computer simulations/analyses, original data are in DTA/DSC formats; simulations in m format. Files in <strong>PARACAT_WP4_20230612_02_Pulse</strong> folder includes Pulsed-EPR spectroscopic measurements and computer simulations/analyses, original data are in DTA/DSC formats; files in m format were used to process the data. <strong>Information on</strong>: specialized abbreviations: <strong>EPR</strong> – Electron Paramagnetic Resonance, <strong>CW</strong> – Continuous Wave EPR, <strong>HYSCORE </strong>– HYperfine Sublevel CORrelation spectroscopy definitions of variables: <strong>Magnetic field, Temperature</strong> units of measurement: <strong>Gauss (G), K</strong>