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Hydrogen Adsorption in an Interpenetrated Dynamic Metal−Organic Framework

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Hydrogen_Adsorption_in_an_Interpenetrated_Dynamic_Metal_Organic_Framework/3069211
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A metal−organic framework Zn(NDC)(4,4‘-Bpe)0.5·xG [NDC = 2,6-naphthalenedicarboxylate; 4,4‘-Bpe = 4,4‘-trans-bis(4-pyridyl)ethylene; G = guest molecules] has been synthesized, structurally characterized, and rationalized to be a two-interpenetrated elongated primitive cubic net. Powder X-ray diffraction and adsorption studies reveal the dynamic feature of the framework, which can take up hydrogen of about 2.0 wt % at 77 K and 40 bar and 0.3 wt % at 298 K and 65 bar.
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2016-03-01
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