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CO<sub>2</sub> Capture by a Rhenium(I) Complex with the Aid of Triethanolamine

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NIAID Data Ecosystem2026-03-09 收录
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A rhenium­(I) tricarbonyl diimine complex with a N,N-dimethyl­form­amide ligand captures one CO2 molecule in the presence of tri­ethanol­amine (TEOA), giving fac-[ReI(bpy)­(CO)3{R2N-CH2CH2O-COO}] (bpy = 2,2′-bipyridine, R = CH2CH2OH). This could be a predominant complex in various photocatalytic CO2 reduction reactions using [ReI(N^N)­(CO)3X]n+ (N^N = diimine ligand; X = monodentate ligand; n = 0, 1) type complexes in the presence of TEOA.

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2016-06-06
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