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Ru-Catalyzed Synthesis of Dihydrofuroquinolines from Azido-cyclopropyl Ketones

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https://figshare.com/articles/dataset/Ru_Catalyzed_Synthesis_of_Dihydrofuroquinolines_from_Azido_cyclopropyl_Ketones/2434066
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资源简介:
An efficient Ru-catalyzed synthesis of dihydrofuroquinolines from azido-cyclopropyl ketones via the reduction–cyclization–rearrangement process is reported. A plausible reaction mechanism for this process is depicted. Additionally, when the reaction was carried out under H2 (1 atm) in the presence of Pd/C, 4-quinolones were obtained in excellent yields.
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2016-02-19
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