Generation of Nickel Siloxycarbene Complexes from Acylsilanes for the Catalytic Synthesis of Silyl Enol Ethers
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A catalytic protocol has been developed to access Fischer carbene nickel complexes using acylsilanes as stable and readily available precursors. The as-generated Fischer carbene complexes exhibit versatile reactivity, including cyclopropanation with alkenes, α-C–H insertion reactions, and two-component C–H addition to norbornene, which demonstrates the broad utility of the nickel(0)/acylsilane system for the catalytic applications of Fischer carbene complexes.
创建时间：
2024-11-25
