Kinetically Controlling Phase Transformations of Crystalline Mercury Selenidostannates through Surfactant Media
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https://figshare.com/articles/dataset/Kinetically_Controlling_Phase_Transformations_of_Crystalline_Mercury_Selenidostannates_through_Surfactant_Media/2424298
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资源简介：
Herein
we report the surfactant-thermal method to prepare two novel one-dimensional
mercury selenidostannates, [DBUH]2[Hg2Sn2Se6(Se2)] (1) and [DBUH]2[Hg2Sn2Se7] (2), where DBU = 1,8-diazabicyclo[5.4.0]undec-7-ene, by applying PEG-400
as the reaction medium. It is worth noting that 1 is
kinetically stable and can be transformed into thermodynamically stable
phase 2 under a longer reaction time. Our strategy “growing
crystalline materials in surfactants” could open a new door
to preparing novel crystals with diverse structures and interesting
properties.
创建时间：
2016-02-19
