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Regioselective Unsymmetrical Tetraallylation of C<sub>60</sub> through Palladium Catalysis

NIAID Data Ecosystem2026-03-06 收录

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https://figshare.com/articles/dataset/Regioselective_Unsymmetrical_Tetraallylation_of_C_sub_60_sub_through_Palladium_Catalysis/2818207 数据链接链接失效反馈

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资源简介：

Regioselective Unsymmetrical Tetraallylation of C60 through Palladium Catalysis

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创建时间：

2016-02-25

富勒烯功能化

有机硅化学

Photochemical reactions of C60 with siliranes (1a−d) afford adducts of four types (2a−5b) as carbosilylated and hydrosilylated C60 derivatives. Characterization of these adducts was conducted using MS

NIAID Data Ecosystem80

Synthesis of C 5 -Symmetric Functionalized [60]Fullerenes by Copper-Mediated 5-Fold Addition of Reformatsky Reagents

富勒烯功能化

手性化合物合成

A variety of Reformatsky reagents were added five times to [60]fullerene in good yield in the presence of a stoichiometric amount of a copper(I) complex. The penta-addition products C60(CH2CO2R)5H (R

NIAID Data Ecosystem70

Synthetic and Structural Studies on the Transition-Metal Fullerene Complexes (η 2 -C 60 )M[(η 5 -Ph 2 PC 5 H 4 ) 2 Ru] and (η 2 -C 60 )M[(η 5 -Ph 2 PC 5 H 4 ) 2 Co] + (PF 6 ) - (M = Pd, Pt) and the Related Compound {[ η 5 -Ph 2 P(O)C 5 H 4 ] 2 Co} + (PF 6 ) -

金属配合物合成

富勒烯功能化

A toluene solution of C60 reacted with an equimolar quantity of M(dba)2 (M = Pd, Pt; dba = dibenzylideneacetone) and (η5-Ph2PC5H4)2Ru or with M(PPh3)4and (η5-Ph2PC5H4)2Ru at room temperature to give t

NIAID Data Ecosystem30

Synthesis of Metal Fullerene Complexes by the Use of Fullerene Halides

富勒烯功能化

金属配合物合成

K(C60R5) (1, R = Me, Ph) was generated by deprotonation of C60R5H (2) and allowed to react with N-fluoropyridinium triflate and N-chloro- and N-bromosuccinimide in benzene at 25 °C for 10 min to obtai

NIAID Data Ecosystem70

Pentaarylfullerenes as Noncoordinating Cyclopentadienyl Anions

金属有机化学

富勒烯功能化

The first example of an early-transition-metal complex involving a pentaarylfullerene was prepared. Instead of half-sandwich complexes, solvent separated ion pairs were obtained in which the pentaaryl

NIAID Data Ecosystem30

Regioselective Unsymmetrical Tetraallylation of C<sub>60</sub> through Palladium Catalysis

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