Highly Enantio- and Diastereoselective Vinylogous Aldol Reaction by LiCl-Assisted BINOL–Titanium Species
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https://figshare.com/articles/dataset/Highly_Enantio_and_Diastereoselective_Vinylogous_Aldol_Reaction_by_LiCl_Assisted_BINOL_Titanium_Species/2518000
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The first highly enantio- and diastereoselective vinylogous aldol reaction between propionyl acetate-derived Brassard’s diene and aldehydes was accomplished by titanium–lithium combined Lewis acid, affording δ-hydroxy-γ-methyl-β-methoxy acrylates. This methodology was utilized in convenient and concise construction of the polypropionate moiety in cystothiazole A and melithiazole C.
创建时间：
2016-02-20
