New Rh(I) and Rh(III) Bisimidazol-2-ylidene Complexes: Synthesis, Reactivity, and Molecular Structures
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https://figshare.com/articles/dataset/New_Rh_I_and_Rh_III_Bisimidazol-2-ylidene_Complexes_Synthesis_Reactivity_and_Molecular_Structures/3610980
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资源简介：
New chelate bis-heterocyclic-carbene complexes of Rh(I) and Rh(III) have been obtained and fully characterized.
The molecular structures of the new species have been determined. The synthesis of the compounds starts from
the bisimidazolium precursors, which are deprotonated with NEt3 under mild reaction conditions, leading to coordination
to the Rh complex. The Rh(III) compounds are generated from Rh(I) and [Rh(II)]2 species, although there is no
apparent oxidizing agent in the reaction media.
创建时间：
2016-08-17
