Platinum Model Studies for Palladium-Catalyzed Oxidative Functionalization of C−H Bonds
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https://figshare.com/articles/dataset/Platinum_Model_Studies_for_Palladium_Catalyzed_Oxidative_Functionalization_of_C_H_Bonds/3301237
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资源简介：
The synthesis of (CN)PtII(acac) complexes (CN
= benzo[h]quinoline, 8-methylquinoline) and their oxidation with PhI(OAc)2 are reported as a model system
for palladium-catalyzed C−H bond functionalization.
Dimeric PtIII−PtIII complexes containing a bridging
acetate ligand are obtained in HOAc, and monomeric
PtIV complexes incorporating alkoxide and acetate ligands
are obtained in MeOH, EtOH, and iPrOH. The implications of these results for the mechanism of analogous Pd-catalyzed reactions is discussed.
创建时间：
2016-05-06
