Unprecedented Enantioselectivity in a Cluster-Based Catalytic System
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https://figshare.com/articles/dataset/Unprecedented_Enantioselectivity_in_a_Cluster-Based_Catalytic_System/12076320
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资源简介：
Catalytic systems based on the clusters [H4Ru4(CO)10{μ-1,2-(P−P)}] and [H4Ru4(CO)10{1,1-(P−P)}] (P−P = (R)-(R)-Ph2PPhFcCHCH3PR2; Fc = ferrocenyl; R = 3,5-CF3Ph
(W001), Ph (W002)) have been used successfully in asymmetric
hydrogenation of prochiral α-unsaturated carboxylic acids
under mild conditions. Enantiomeric excesses of 42−92% and
conversion rates in excess of 99% were observed.
创建时间：
2007-08-13
