Palladium-Catalyzed Synthesis of Benzosilolo[2,3-b]indoles via Cleavage of a C(sp3)–Si Bond and Consequent Intramolecular C(sp2)–Si Coupling
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Palladium_Catalyzed_Synthesis_of_Benzosilolo_2_3_i_b_i_indoles_via_Cleavage_of_a_C_sp_sup_3_sup_Si_Bond_and_Consequent_Intramolecular_C_sp_sup_2_sup_Si_Coupling/2639518
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An efficient process involving Pd-catalyzed selective cleavage of a C(sp3)–Si bond and consequent intramolecular C(sp2)–Si coupling has been developed, affording benzosilolo[2,3-b]indoles as a new type of silicon-bridged polyheteroarene in excellent yields. Aldehyde was found for the first time to be able to promote the efficiency of the catalytic process remarkably.
创建时间：
2016-02-23
