A Concise Approach for the Total Synthesis of Pseudolaric Acid A
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https://figshare.com/articles/dataset/A_Concise_Approach_for_the_Total_Synthesis_of_Pseudolaric_Acid_A/2650669
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资源简介：
A new strategy for the stereoselective total synthesis of natural product pseudolaric acid A (1) was accomplished in 16 steps from commercially available starting material, featuring a samarium diiodide (SmI2)-mediated intramolecular alkene-ketyl radical cyclization and a ring-closing metathesis (RCM) reaction to stereoselectively cast the unusual trans-fused [5–7]-bicyclic core of pseudolaric acid A (1).
创建时间：
2016-02-23
