Near-Infrared Luminescent and Magnetic Cyano-Bridged Coordination Polymers Nd(phen)n(DMF)m[M(CN)8] (M = Mo, W)
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New cyano-bridged coordination polymers [Nd(phen)2(DMF)2(H2O)Mo(CN)8]·2H2O (1) and [Nd(phen)(DMF)5M(CN)8]·xH2O [M = Mo (2), W (3); phen = 1,10-phenanthroline] have one-dimensional structures with variable number of phenanthroline ligands. Compounds exhibit photoluminescence in the near-infrared region and ferromagnetic Nd3+–M5+ interactions.
创建时间:
2016-02-22



