Rich Coordination Chemistry of π‑Acceptor Dibenzoarsole Ligands
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https://figshare.com/articles/dataset/Rich_Coordination_Chemistry_of_Acceptor_Dibenzoarsole_Ligands/4789597
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资源简介：
A series of dibenzoarsole (also known
as 9-arsafluorene) derivatives have been prepared, and their coordination
chemistry has been investigated. The different ligand topology and
the arsenic substituents govern the reactivity of the ligands. We
report various crystal structures of palladium and platinum complexes
derived from this family of ligands. The biphenyl backbone of the
bridged bidentate ligands allows very flexible coordination. We have
also studied the application of an allylic Pd complex in nucleophilic
substitution reactions, revealing that the benzoarsole substituent
is susceptible to metal insertion.
创建时间：
2017-03-27
