(A) Tabulation of typical C–N stretching frequencies of thiocyanates, isothiocyanates, and isocyanates [42,43,46,47]. (B) Iron cyanide and carbonyl stretching frequencies as found with mature [NiFe]–and [FeFe]–hydrogenases [4].
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* In oxidized [FeFe]–hydrogenases, one CO ligand can be found in a ‘bridging’ position [48] (A) Tabulation of typical C–N stretching frequencies of thiocyanates, isothiocyanates, and isocyanates [42,43,46,47]. (B) Iron cyanide and carbonyl stretching frequencies as found with mature [NiFe]–and [FeFe]–hydrogenases [4].
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2015-07-17
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