Chiral-at-Metal Rh(III) Complex Catalyzed Cascade Reduction-Michael Addition Reaction
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下载链接：
https://figshare.com/articles/dataset/Chiral-at-Metal_Rh_III_Complex_Catalyzed_Cascade_Reduction-Michael_Addition_Reaction/10277621
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资源简介：
An enantioselective
three-component cascade reduction-Michael addition
reaction catalyzed by chiral-at-metal Rh(III) complexes has been developed.
With a Hantzsch ester as the hydride source, a number of malononitrile
derivatives were prepared in good yields and excellent enantioselectivities.
A model that accounts for the origin and influence factors of the
stereoselectivity has been proposed based on experiments.
创建时间：
2019-10-29
