Remarkable 1,6-Acyclic Diastereoselection in the Coupling of a Novel Butadienyl Di-indium Compound with Aldehydes
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https://figshare.com/articles/dataset/Remarkable_1_6-Acyclic_Diastereoselection_in_the_Coupling_of_a_Novel_Butadienyl_Di-indium_Compound_with_Aldehydes/3648294
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资源简介:
The reaction between a novel butadienyl di-indium reagent and aldehydes showed remarkable 1,6-diastereoselectivity to give acetylenic diol products as a single diastereomer. A bicyclic transition state formed through intramolecular chelation control was proposed that might account for the high 1,6-diastereoselection result.
创建时间:
2016-08-18



