1,4,7-Triazacyclononane Ligands Bearing Tertiary Alkyl Nitrogen Substituents
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The first synthesis of 1,4,7-tri-tert-butyl-1,4,7-triazacyclononane (tBu3tacn) and its adamantyl analog Ad3tacn are described. CrII, MnII, FeII, CoII, NiII, and CuI compounds of tBu3tacn are reported: the steric properties of this ligand enforce four-coordinate geometries except in the case of five-coordinate CrII, enabling design of pseudotetrahedral compounds bearing this tridentate redox-inert ancillary ligand.
创建时间：
2016-02-18
