Synthesis of Pyrazines from Rhodium-Catalyzed Reaction of 2H‑Azirines with N‑Sulfonyl 1,2,3-Triazoles
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An efficient synthetic route to a wide range of trisubstituted pyrazines is developed from Rh-catalyzed reaction of 2H-azirines with N-sulfonyl-1,2,3-triazoles through the elimination of nitrogen molecule and arylsulfinic acid. The present reaction proceeds through formation of in situ generated dihydropyrazines.
创建时间：
2016-02-14
