Polynuclear Homo- or Heterometallic Palladium(II)−Platinum(II) Pentafluorophenyl Complexes Containing Bridging Diphenylphosphido Ligands. 8.<sup>†</sup> Syntheses and Reactivity of the Tetranuclear [Pt<sub>4</sub>(μ<sub>2</sub>-PPh<sub>2</sub>)<sub>3</sub>{μ<sub>3</sub>-PPh(1,2-η<sup>2</sup>-Ph)-κ<sup>3</sup><i>P</i>}(C<sub>6</sub>F<sub>5</sub>)<sub>4</sub>] Cluster
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数据链接：
https://figshare.com/articles/dataset/Polynuclear_Homo-_or_Heterometallic_Palladium_II_Platinum_II_Pentafluorophenyl_Complexes_Containing_Bridging_Diphenylphosphido_Ligands_8_sup_sup_Syntheses_and_Reactivity_of_the_Tetranuclear_Pt_sub_4_sub_sub_2_sub_-PPh_sub_2_sub_sub_3_sub_sub_3_sub_-PPh_1_/3762225数据链接链接失效反馈
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资源简介：
The reaction of [NBu4]2[{(C6F5)2Pt(μ-PPh2)2Pt(μ-Cl)}2] with AgClO4 in CH2Cl2 (1:2 mol ratio) gives the neutral tetranuclear compound [Pt4(μ-PPh2)3{μ3-PPh(1,2-η2-Ph)-κ3P)}(C6F5)4] (5), a 58-electron cluster that displays three Pt−Pt bonds and a 1,2-η2-Ph (of the PPh2 ligand) Pt interaction. This complex reacts with bipy or phen (L−L), giving the tetranuclear clusters [Pt4(μ-PPh2)4(C6F5)4(L−L)] (L−L = bipy 6, phen 7), while its reaction with CO in CH2Cl2 renders [{Pt2(μ-PPh2)2(C6F5)2(CO)}2] (8). The molecular structures of complexes 5 and 6 have been established by X-ray crystallography, and the structure of 8 is inferred by 31P NMR spectroscopy.
创建时间：
2016-08-26
