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Gold Catalysis: Regio- and Stereoselective Total Synthesis of Xyloketals D and G and the Related Natural Product Alboatrin

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Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Gold_Catalysis_Regio_and_Stereoselective_Total_Synthesis_of_Xyloketals_D_and_G_and_the_Related_Natural_Product_Alboatrin/2433673
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A new and efficient one-pot desilylation–gold-catalyzed cycloisomerization of alkynes containing a silyl-protected phenolic −OH and a free alcoholic −OH unit leads selectively to the formation of tetrahydrofuranobenzopyran ring system. This approach has been used for the regio- and stereoselective synthesis of xyloketal D, xyloketal G, and the related natural product alboatrin.
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2016-02-19
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