Desymmetrization Strategy to Achieve Triptycene-Based 3,6-Dimethoxytriphenylenes via Oxidative Cyclodehydrogenation [Data]
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To achieve a highly symmetric triptycene based hexamethoxytriphenylene in high yield of 97 %, a less symmetric triptycene (C3v) is necessary as precursor for cyclodehydrogenative Scholl-type oxidation, by taking into account the regioselectivity of the C-C bond formation controlled by attached methoxy groups. In addition, Scholl-type oxidations and photochemical reactions are compared.
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heiDATA创建时间：
2022-01-24
