Calixanthomycin A: Asymmetric Total Synthesis and Structural Determination
收藏NIAID Data Ecosystem2026-03-12 收录
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https://figshare.com/articles/dataset/Calixanthomycin_A_Asymmetric_Total_Synthesis_and_Structural_Determination/14061645
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资源简介：
We report the first asymmetric total
synthesis and structural determination
of calixanthomycin A. Taking advantage of a modular strategy, a concise
approach was developed to assemble the hexacyclic skeleton with both
enantiomers of the lactone A ring. Stereoselective glycosylation coupled
the angular hexacyclic framework with a monosaccharide fragment to
produce calixanthomycin A and its stereoisomers. This enable us to
determine and assign the absolute configuration of C-25 (25S) and
monosaccharide (derivative of l-glucose).
创建时间：
2021-02-19
