Synthesis, Structure, and Spectroscopy of Silaallyl− and Silapentadienyl−Iridium−Phosphine Complexes<sup>1</sup>
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Silaallyl− and silapentadienyl−iridium−phosphine complexes have been synthesized via the reaction of “(Me)Ir(PMe3)3” with vinyl- and butadienyldimethylsilanes. Upon heating, these complexes lose methane and undergo a variety of reactions, including C−H bond activation to produce a five-membered iridasilacycle, CC bond coordination to generate an η1,η2-silapentadienyl ligand, and decomposition.
创建时间：
2007-07-30
