Mechanistic Study of the Oxidative Coupling of Styrene with 2‑Phenylpyridine Derivatives Catalyzed by Cationic Rhodium(III) via C–H Activation
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https://figshare.com/articles/dataset/Mechanistic_Study_of_the_Oxidative_Coupling_of_Styrene_with_2_Phenylpyridine_Derivatives_Catalyzed_by_Cationic_Rhodium_III_via_C_H_Activation/2420110
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资源简介：
The Rh(III)-catalyzed
oxidative coupling of alkenes with arenes
provides a greener alternative to the classical Heck reaction for
the synthesis of arene-functionalized alkenes. The present mechanistic
study gives insights for the rational development of this key transformation.
The catalyst resting states and the rate law of the reaction have
been identified. The reaction rate is solely dependent on the catalyst
and alkene concentrations, and the turnover-limiting step is the migratory
insertion of the alkene into a Rh–C(aryl) bond.
创建时间：
2016-02-19
