Synthesis of Sterically Crowded Polyarylated Boron-Dipyrromethenes
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https://figshare.com/articles/dataset/Synthesis_of_Sterically_Crowded_Polyarylated_Boron_Dipyrromethenes/2596189
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A rapid synthetic route for polyarylated boron-dipyrromethenes using hexabromo boron-dipyrromethene as the key synthon is described. The X-ray structure revealed that the polyarylated BODIPY adopts a propeller-like conformation. These compounds exhibit red-shifted absorption and fluorescence bands with decent quantum yields and reversible oxidation and reduction waves when compared to unsubstituted boron-dipyrromethenes.
创建时间：
2016-02-22
