Chiral Hexanuclear Ferric Wheels
收藏NIAID Data Ecosystem2026-03-07 收录
下载链接：
https://figshare.com/articles/dataset/Chiral_Hexanuclear_Ferric_Wheels/2544592
下载链接
链接失效反馈官方服务：
资源简介：
The homochiral iron(III) wheels [Fe6{(S)-pedea}6Cl6] and [Fe6{(R)-pedea)}6Cl6] [(R)- and (S)-2; pedea = phenylethylaminodiethoxide]
exhibit high optical activities and antiferromagnetic exchange. These
homochiral products react with each other, producing the centrosymmetric,
crystallographically characterized [Fe6{(S)-pedea}3{(R)-pedea}3Cl6] diastereomer [(RSRSRS)-2]. 1H NMR and UV–vis studies indicate that exchange processes
are slow in both homo- and heterochiral systems but that, upon combination,
the reaction between (R)- and (S)-2 occurs quickly.
创建时间：
2016-02-22
