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Synthesis of Benzosiloles by Intramolecular <i>anti</i>-Hydroarylation via <i>ortho</i>-C–H Activation of Aryloxyethynyl Silanes

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NIAID Data Ecosystem2026-03-10 收录
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Straightforward synthesis of benzosiloles was achieved by the invention of Pd/acid-catalyzed intramolecular anti-hydroarylation of aryloxyethynyl­(aryl)­silanes via ortho-C–H bond activation. The aryloxy group bound to the ethynyl carbon is the key factor for this transformation.

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2017-09-26
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