Synthesis of zwitterionic phosphapalladacycles: unusual reactivity pattern of six-membered P,N-chelates
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https://figshare.com/articles/dataset/Synthesis_of_zwitterionic_phosphapalladacycles_unusual_reactivity_pattern_of_six-membered_P_N-chelates/6719861
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资源简介：
A cyclometalation motif has been
discovered in the unprecedented reaction of Pd(II) precursors with
simple pentane-2,4-diyl based aminoalkyl-phosphines. The unique six-membered
zwitterionic palladacycles can easily be synthesized in the presence
of 1 molar equiv of oxidant in high yields in a pure form. A comparison
between the analogous ligands of different tether lengths revealed
that the formation of the zwitterionic palladacycles is the exclusive
privilege of the six-membered rings.
创建时间：
2018-06-28
